diff --git a/esphome/build_helpers/pch.py b/esphome/build_helpers/pch.py
index dc23942c8e..bd13726d85 100644
--- a/esphome/build_helpers/pch.py
+++ b/esphome/build_helpers/pch.py
@@ -9,6 +9,7 @@ import os
 from pathlib import Path
 import posixpath
 import re
+import sys
 
 from esphome.build_helpers.ccache import effective_ccache_basedir, parse_enable_env
 from esphome.const import (
@@ -47,10 +48,18 @@ PCH_DEFAULT_HEADERS = ("esphome/core/pch_prefix.h",)
 
 # PlatformIO platforms that do not take the pch script
 PCH_SCRIPT_EXCLUDED_PLATFORMS = frozenset(
+    {
+        PLATFORM_NRF52,
+    }
+)
+
+# The GCC 10.3 of LibreTiny only loads its own .gch back on Linux: elsewhere
+# the compiler is loaded at a new address each run, which GCC accepts from
+# version 12. Remove once LibreTiny ships GCC 12 or newer
+PCH_SCRIPT_LINUX_ONLY_PLATFORMS = frozenset(
     {
         PLATFORM_BK72XX,
         PLATFORM_LN882X,
-        PLATFORM_NRF52,
         PLATFORM_RTL87XX,
     }
 )
@@ -94,7 +103,10 @@ def pch_script_enabled() -> bool:
     """Whether this PlatformIO build takes the pch script."""
     from esphome.core import CORE
 
-    return pch_enabled() and CORE.target_platform not in PCH_SCRIPT_EXCLUDED_PLATFORMS
+    platform = CORE.target_platform
+    if platform in PCH_SCRIPT_LINUX_ONLY_PLATFORMS and sys.platform != "linux":
+        return False
+    return pch_enabled() and platform not in PCH_SCRIPT_EXCLUDED_PLATFORMS
 
 
 def pch_header_text(include_headers: Iterable[str]) -> str:
diff --git a/tests/unit_tests/build_helpers/test_pch.py b/tests/unit_tests/build_helpers/test_pch.py
index a64e9525e6..0ea8215738 100644
--- a/tests/unit_tests/build_helpers/test_pch.py
+++ b/tests/unit_tests/build_helpers/test_pch.py
@@ -109,14 +109,27 @@ def test_pch_checksum_tracks_closure_content(tmp_path: Path) -> None:
     assert base != pch.pch_checksum(tmp_path, ["root.h"], ["id"])
 
 
-@pytest.mark.parametrize("platform", ["esp32", "esp8266", "rp2"])
+@pytest.mark.parametrize(
+    "platform", ["bk72xx", "esp32", "esp8266", "ln882x", "rp2", "rtl87xx"]
+)
 def test_pch_script_enabled(platform: str, monkeypatch: pytest.MonkeyPatch) -> None:
+    monkeypatch.setattr(pch.sys, "platform", "linux")
     CORE.data[KEY_CORE] = {KEY_TARGET_PLATFORM: platform}
     assert pch.pch_script_enabled()
     monkeypatch.setenv("ESPHOME_PCH_ENABLE", "0")
     assert not pch.pch_script_enabled()
 
 
+@pytest.mark.parametrize("host", ["darwin", "win32"])
+@pytest.mark.parametrize("platform", sorted(pch.PCH_SCRIPT_LINUX_ONLY_PLATFORMS))
+def test_pch_script_linux_only_platform(
+    platform: str, host: str, monkeypatch: pytest.MonkeyPatch
+) -> None:
+    monkeypatch.setattr(pch.sys, "platform", host)
+    CORE.data[KEY_CORE] = {KEY_TARGET_PLATFORM: platform}
+    assert not pch.pch_script_enabled()
+
+
 @pytest.mark.parametrize("platform", sorted(pch.PCH_SCRIPT_EXCLUDED_PLATFORMS))
 def test_pch_script_excluded_platform(platform: str) -> None:
     CORE.data[KEY_CORE] = {KEY_TARGET_PLATFORM: platform}