diff --git a/esphome/components/libretiny/__init__.py b/esphome/components/libretiny/__init__.py
index c63d6d7faa..93b66888da 100644
--- a/esphome/components/libretiny/__init__.py
+++ b/esphome/components/libretiny/__init__.py
@@ -261,6 +261,10 @@ async def component_to_code(config):
     cg.add_build_flag(f"-DUSE_LIBRETINY_VARIANT_{config[CONF_FAMILY]}")
     cg.add_define("ESPHOME_BOARD", config[CONF_BOARD])
     cg.add_define("ESPHOME_VARIANT", FAMILY_FRIENDLY[config[CONF_FAMILY]])
+    # LibreTiny uses MULTI_NO_ATOMICS because platforms like BK7231N (ARM968E-S) lack
+    # exclusive load/store (no LDREX/STREX). std::atomic RMW operations require libatomic,
+    # which is not linked to save flash (4-8KB). Even if linked, libatomic would use locks
+    # (ATOMIC_INT_LOCK_FREE=1), so explicit FreeRTOS mutexes are simpler and equivalent.
     cg.add_define(ThreadModel.MULTI_NO_ATOMICS)
 
     # force using arduino framework
diff --git a/esphome/const.py b/esphome/const.py
index b4cd3cfd1c..2b6b60d395 100644
--- a/esphome/const.py
+++ b/esphome/const.py
@@ -36,7 +36,30 @@ class Framework(StrEnum):
 
 
 class ThreadModel(StrEnum):
-    """Threading model identifiers for ESPHome scheduler."""
+    """Threading model identifiers for ESPHome scheduler.
+
+    ESPHome currently uses three threading models based on platform capabilities:
+
+    SINGLE:
+        - Single-threaded platforms (ESP8266, RP2040)
+        - No RTOS task switching
+        - No concurrent access to scheduler data structures
+        - No atomics or locks required
+        - Minimal overhead
+
+    MULTI_NO_ATOMICS:
+        - Multi-threaded platforms without hardware atomic RMW support (e.g. LibreTiny BK7231N)
+        - Uses FreeRTOS or another RTOS with multiple tasks
+        - CPU lacks exclusive load/store instructions (ARM968E-S has no LDREX/STREX)
+        - std::atomic cannot provide lock-free RMW; libatomic is avoided to save flash (4–8 KB)
+        - Scheduler uses explicit FreeRTOS mutexes for synchronization
+
+    MULTI_ATOMICS:
+        - Multi-threaded platforms with hardware atomic RMW support (ESP32, Cortex-M, Host)
+        - CPU provides native atomic instructions (ESP32 S32C1I, ARM LDREX/STREX)
+        - std::atomic is used for lock-free synchronization
+        - Reduced contention and better performance
+    """
 
     SINGLE = "ESPHOME_THREAD_SINGLE"
     MULTI_NO_ATOMICS = "ESPHOME_THREAD_MULTI_NO_ATOMICS"